Valency = No. of electrons in valence shell
For atoms with more than 4 valence electrons-
Valency = 8- No. of electrons in its outermost shell
In SF6, Sulphur is present in the 3rd group which means it can expand its octet by donating all of its 6 electrons.
Hence, it donates all the 6 electrons to each fluoride atom.
Final Answer:
Hence, the valency of Sulphur in SF6 is 6.