Alkali metals elements of group 1 in which the last electron enters in s orbital and it has ns1 electronic configuration.
Halogen elements are the elements of group seventeen in which the last electron enters in p orbital and ns2 np7 electronic configuration.
An alkali element in period 3 and halogen in period 2 is sodium and fluorine respectively.
Final Answer:
Hence the correct answer is sodium and fluorine respectively.