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When ethanol reacts with phosphorus trichloride in the presence of heat ethyl chloride and phosphorus acid is produced.
3C2H5OH + PCl3 → 3C2H5Cl + H3PO3
When ethanol reacts with phosphorus pentachloride in the presence of heat ethyl chloride hydrochloric acid and phosphoryl chloride is produced.
C2H5OH+PCl5 → C2H5Cl + HCl + POCl3.
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