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When adsorbate (gas or liquid mostly) absorbed then their entropy get reduced i.e. ΔS is negative. For every spontaneous process ΔG must be negative. ΔG=ΔH-TΔS, as TΔS is positive(ΔS is negative) ΔH must be negative in order to make ΔG negative . Hence ΔH is negative that means the reaction is exothermic. Hence every adsorption reactions are exothermic.
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