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The correct answer is option D,roasting i.e. heating pyrites like iron pyrite, cu pyrite in presence of air/O2 is called roasting. The reaction can be shown as follows:
2Cu2S + 3O2 →2Cu2O + 2SO2
While option A i.e. smelting is a part of benefaction, option B i.e. calcination is for carbonate ores and option C , liquation is a process of purification.
Hence, the correct answer is option D.
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