Consider a titration of potassium dichromate solution with acidified Mohr's salt solution using diphenylamine as indicator. The number of moles of Mohr's salt required per mole of dichromate is

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Mohr’s salt is a mixture of ferrous sulfate and ammonium sulfate.

Mohr’s salt is FeSO4 ( NH4 )2SO4

Potassium dichromate oxidizes ferrous sulfate.

Reaction occurs: .

K2Cr2O4 + 6FeSO4 + 7H2SO4 → K2SO4 + Cr42( SO4 ) 3 + 3Fe42( SO4 ) 3 + 7H2O

6 moles of Ferrous sulphate reacts with 1 mole of potassium dichromate.

Thus, 6 moles of Mohr's salt are required for 1 mole of dichromate.

The option(D): 6 is correct.

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